Abstract
Abstract L X-ray emission spectra in the energy region of the Cr 2p threshold on Cr compounds were measured and analysed using tunable synchrotron radiation. The X-ray absorption and emission spectra (XAES) of Cr (VI) are very different from those of Cr (III). It is considered that the difference in the soft X-ray emission is mainly attributed to the effect of the covalency in bonding, because the transition intensity of the Kβ 2 spectral line is sensitive for the valence electronic configuration. Therefore, it follows that XAES is very sensitive to the ligand environment in Cr compounds and relatively insensitive to the metal oxidation state, as Grush et al. suggested for Mn complexes [J. Electron. Spectros. Relat. Phenom. 92 (1998) 225].
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of Electron Spectroscopy and Related Phenomena
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
