Abstract

The distribution of the diffuse scattering intensity of uranium dioxide single crystals has been studied before and after irradiation by reactor neutrons with doses of 1014, 1015 and 5.1016 fissions cm-3. It has been found that irradiation effects occurred only at 5.1016 fissions cm-3. The {002}k planes of irradiated UO2 and the {22{\bar 4}}k and {11{\bar 3}}k planes of unirradiated crystals have been observed as planes of high diffuse intensity. In unirradiated crystals the measured relative intensities around the 335 reciprocal-lattice point are in fair agreement with calculations using the Jahn formula, i.e. they have a maximum in the [33{\bar 1}] direction. In irradiated samples, however, there exists a weak [002] maximum. This change in the distribution cannot be interpreted by Stokes-Wilson scattering alone and the extra intensity may be explained by the scattering of X-rays from defect modes of lattice vibrations.

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