Abstract
Abstract The mesophase structure of a series of sixteen cholesterol-based liquid crystalline materials based on cyclosiloxane backbones is examined. The co-existence of two layer types (full and partial interdigitation of cholesterol mesogens) in the mesophase is examined as a function of ring size, composition, and spacer length. The relative X-ray intensities from each layer type are discussed as a function of these variables. An increase in the ring size and cholesterol composition, and a decrease in the spacer group all result in more partially interdigitated packing. Molecular modeling calculations performed on the mesogens and macromolecules examine relative differences in the orientational relationships and flexibility of mesogens.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.