X-ray diffraction study of DL-1,4-dimethyl-2,5-dioxabicyclo[2.2.1]heptane-3,6-dione: the sense of twist and folding

Abstract

The title dilactone exists in a crystalline state (110 K) as enantiomeric synchro-(+,+)-(R,R)- and synchro-(–,–)-(S,S)-twist forms (τ0 = |1.8°|) with the retention of C2 symmetry, linked by infinite zig-zag heterochiral chains (space group C2/c) by mutual H-bonds of the CH2–H‥O=C type.