Work distribution of a colloid in an elongational flow field and under Ornstein-Uhlenbeck noise.

Abstract

The study of thermodynamic properties of microscopic systems, such as a colloid in a fluid, has been of great interest to researchers since the discovery of the fluctuation theorem and associated laws of stochastic thermodynamics. However, most of these studies confine themselves to systems where effective fluctuations acting on the colloid are in the form of delta-correlated Gaussian white noise (GWN). In this study, instead, we look into the work distribution function when a colloid trapped in a harmonic potential moves from one position to another in a fluid medium with an elongational flow field where the effective fluctuations are given by the Ornstein-Uhlenbeck noise, a type of colored noise. We use path integrals to calculate this distribution function and compare and contrast its properties to the case with GWN. We find that the work distribution function turns out to be non-Gaussian as a result of the elongational flow field but continues to obey the fluctuation theorem in both types of noise. Further, we also look into the effects of the various system parameters on the behavior of work fluctuations and find that although the distribution tends to broaden with increasing noise intensity, increased correlation in fluctuations acts to oppose this effect. Additionally, the system is found to consume heat from the surroundings at early times and dissipate it into the media at later times. This study, therefore, is a step towards gaining a better understanding of the thermodynamic properties of colloidal systems under nonlinear complex flows that also display correlated fluctuations.