Abstract
ABSTRACT Alkynylaluminum reagents are good nucleophiles for organic reactions because of their high reactivities, low toxicities, and the high Lewis acidity of the aluminum center. Therefore, alkynylaluminum reagents are widely applied in many of organic reactions. This review summarizes the recent advance of the alkynylaluminum reagents applied in cross-coupling reactions, involving various reaction systems, properties of reaction and synthetic application.
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