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https://doi.org/10.1021/om1007506
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Cite Journal: Organometallics |  Publication Date: Aug 17, 2010 |
 Citations: 78 |
Affiliation: École Polytechnique Fédérale de Lausanne
Isomerization and olefin exchange experiments show that β-H elimination is kinetically viable but thermodynamically unfavorable in [(MeNN2)Ni-alkyl] complexes. The intermediacy of Ni-hydride species was corroborated by a trapping experiment. The alkyl complex [(MeNN2)Ni-propyl] catalyzes olefin isomerization.
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