Wet chemical synthesis of monocalcium aluminate

Abstract

Monocalcium aluminate, CaAl 2O 4, is the main constituent of calcium aluminate cements (CACs), which are used in a wide range of applications. Conventionally, monocalcium aluminate is prepared by long lasting sintering of the solid oxide mixture in temperatures exceeding 1400 °C. The Pechini process is an alternative, low temperature polymeric precursor route for the synthesis of high purity oxides. In the present work, CaAl 2O 4 is prepared through the Pechini technique. Conventional solid-state synthesis is used in order to compare the final products with those obtained through the Pechini technique. As it is concluded, the Pechini technique can be successfully applied for the synthesis of CaAl 2O 4. Its formation requires a 3-h sintering at 900 °C. The final product is crystalline CaAl 2O 4 of high purity, without any impurities of reactants or secondary phases.