Abstract

This study presents a dual-biomimetic polymer coating with improved wear and corrosion resistance, inspired by natural biological structures of shells and superhydrophobic surfaces. The coating is composed of alternating hard epoxy resin layers, modified with benzotriazole-functionalized silica for corrosion protection, and soft fluorocarbon resin layers, enhanced with graphene oxide for improved mechanical properties. Surface textures were added using a soft template method to boost hydrophobicity and reduce wear. The coating demonstrated excellent hardness, impact resistance, and corrosion protection, particularly in simulated seawater. Additionally, surface textures further minimized wear by trapping debris. This design strategy offers a promising approach for advanced polymer coatings in marine, machinery, and chemical applications, combining durability, protection, and self-healing properties.

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