Abstract
Water-soluble star polymers were synthesized by reversible addition-fragmentation chain transfer (RAFT) polymerization of N-vinyl-1,2,4-triazole (NVTri), which is a non-conjugated N-vinyl monomer having an aromatic heterocycle. Four-arm poly(NVTri)s having low polydispersities and controlled molecular weights were obtained using a xanthate-type tetrafunctional chain transfer agent (CTA). Amphiphilic star block copolymers having inner water-soluble segments connected to the core were synthesized by RAFT polymerization of N-vinylcarbazole (NVC) using poly(NVTri) star as a macro-CTA. In contrast, RAFT polymerization of NVTri using poly(NVC) star afforded star block copolymers with block arms consisting of inner optoelectronic poly(NVC) segment and outer hydrophilic poly(NVTri) segment. Assembled structures of these amphiphilic star block copolymers formed in selective solvents and characteristic optoelectronic properties were evaluated by dynamic light scattering (DLS), UV–vis, and fluorescence spectroscopic methods.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
