Water Soluble Trianiline Containing Polyurethane (TAPU) as an Efficient Corrosion Inhibitor for Mild Steel

Abstract

Novel trianiline containing water soluble polyurethane (TAPU) was synthesized by polymerization of polyethylene glycol, toluene diisocyanate and amine-capped aniline trimer. The influence of TAPU on the corrosion inhibition of mild steel in 1 M HCl was investigated using weight loss measurements, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS). The performance of TAPU on the corrosion inhibition of mild steel was also evidenced by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and atomic force microscope (AFM). Results confirmed that the adsorption of TAPU on the mild steel surface and consequent inhibition of the corrosion process. The inhibition efficiency (IE%) increased with a rise in TAPU concentration, reaching a value up to 97% at a concentration of 200 mg/l. Potentiodynamic polarization curves showed that the TAPU affected both cathodic and anodic protection and was a mixed type inhibitor in HCl corrosive medium. Adsorption isotherm studies confirmed that the adsorption of TAPU on the mild steel surface in 1 M HCl solution obeyed Langmuir adsorption isotherm. EDS analysis determined the adsorption of TAPU molecules on the steel surface, and the absorbed TAPU provided an effective corrosion inhibition in 1 M HCl solution from observation of surface morphology by SEM and AFM.