Abstract
Indirect determination of partition coefficients of volatile substances in the system oleyl alcohol—water for analysis of quantitative structure—activity relationships is discussed. Water and oleyl alcohol were used as stationary liquid phases in gas—liquid chromatography. In order to correct the results for adsorption effects, two new procedures using a standard substance were suggested. The procedures were compared with a procedure used by Conder et al. Comparison of molar hydration enthalpies and entropies derived from experimental results of a series of aliphatic alcohols with calorimetric data proved that all procedures under consideration yielded true partition coefficients.
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Schedule a callMore From: Journal of Chromatography B: Biomedical Sciences and Applications
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