Waste management and salt recovery from solid residue of tannery common effluent treatment plant

Abstract

ABSTRACT The considerable amount of solid residue generated by the common effluent treatment plant (CETP) of tanneries needs adequate treatment and reclamation before ending up in the environment as solid waste. A sustainable process aiming at tannery CETP waste minimisation and its reuse for sodium chloride salt recovery is presented. The integrated approach consists of dissolution, decolorisation, filtration, evaporation, and crystallization as unit operations. Lab-scale parametric studies have been undertaken to investigate the effects of various parameters at different process stages on product (sodium chloride) yield and quality. The developed process resulted in the recovery of 93% NaCl, having a purity of ∼98.5%. The optimised operating conditions were tested on a bench-scale system (15 kg batch scale of solid residue) deploying solar energy for evaporation-crystallization, and process feasibility was established. An economic analysis was performed, and the techno-economic feasibility was demonstrated to produce 15,733 tons per annum (TPA) of NaCl from 20,000 TPA of solid residue. The techno-economic analysis favours the treatment of tannery CETP waste with the method specified. The proposed scheme can tackle waste management and reuse the recovered product in the tanning process.