Abstract

Comprehensive SummaryA series of nickel‐doped copper tungstate/oxygen‐rich TiO2 heterojunction‐constructed composites of xNi‐CuWO4/OTiO2 were successfully prepared to demonstrate the enhancement of the visible‐light photoactivity through promoting the photogenerated charge carrier separation efficiency. Of all these composites, 0.2Ni‐CuWO4/OTiO2 exhibits excellent and stable visible light photoactivity for the photooxidative coupling of benzylamine to the corresponding N‐benzyl‐1‐phenymethanimine (BPMI) in air atmosphere. The conversion of benzylamine and the selectivity to BPMI reach 97% and 99%, respectively. The catalyst shows good cyclability with the conversion of benzylamine decreasing just by 22% after being repeated six times with the well‐maintained selectivity of BPMI. The composite also exhibits excellent photo‐bactericidal ability, which greatly inhibits the reproducing of both the Gram‐positive bacteria (e.g., S. epidermidis) and Gram‐negative bacteria (e.g., E. coli).

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