Abstract

AbstractHerein, we report a vibration‐induced emission molecule, 9,14‐diphenyl‐dihydrodibenzo[a,c]phenazines (DPAC), compound‐catalyzed C−H difluoroalkylation of (hetero)arenes under visible light conditions. This method demonstrates the promising potential of vibration‐induced‐emission (VIE) molecules in photocatalysis and facilitates a metal‐free synthetic approach for difluoroalkyl (hetero)arenes with broad substrate scope and functional group tolerance.

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