Abstract
The Jahn—Teller effect in the pE″ Rydberg series on NH 3 is investigated within a simple multi-channel-quantum-defect-type model. The parameters of the model are determined from recently observed infrared-optical double resonance spectra of the B̃ 1E″ (3p x,y band system. Jahn—Teller induced vibrational autoionization effects and pronounced perturbations of high Rydberg members are analyzed. a
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