Abstract
Franck-Condon factors (vibrational transition probabilities) and r-centroids have been evaluated by an approximate analytical method for the A-X system of the MgF molecule. The r-centroids for a given band (ν′, ν″) have been found to decrease smoothly with increasing wavelengths λ ν′ν″. The value of δr̆ ≡ (r̆ ν′ + 1,ν ″ + 1-r̆ ν′, ν″ in a sequence has also been found to remain constant.
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