Abstract

The infrared absorption spectrum of liquid 1,3-difluorobenzene has been obtained in the region 2–22μ with the aid of LiF, NaCl, and KBr prisms. The contours of the strong infrared bands of the gaseous phase have also been observed in the region 5–22μ. The Raman spectrum of the liquid has been photographed with a three-prism glass spectrograph of linear dispersion 15 A/mm at 4358A, and depolarization ratios have been measured for the stronger Raman bands. A complete assignment of fundamental vibration frequencies is given and the spectra are interpreted in detail.

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