Abstract
The infrared absorption spectra of gaseous and liquid CF2:CHCl have been obtained in the regions 2–22μ and 2–38μ, respectively, with the aid of LiF, NaCl, KBr, and KRS-5 prisms. The Raman spectrum of the liquid phase has been photographed with a three-prism glass spectrograph of linear dispersion 15 A/mm at 4358A. Relative intensities and depolarization ratios have been measured for the stronger Raman bands. A complete assignment of fundamental vibration frequencies is given, the spectra are interpreted in detail, and thermodynamic functions are calculated for the temperature range 253–600°K.
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