Abstract

The Raman and IR spectra of six 1,3,2-oxaazaphospholanes with a tri- and tetracoordinated phosphorus atom were obtained. The bands were assigned, and the spectroscopic features of the oxaazaphospholane ring were noted. Assumptions regarding the peculiarities of the three-dimensional structure of the molecules were made on the basis of the change in the characteristic frequencies on passing from trivalent phosphorus compounds to tetracoordinated phosphorus compounds.

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