Abstract
The i.r. (250–4000 cm.–1) and Raman spectra (2000–2500 cm.–1) of the cis- and trans-isomers of dicyanotetrakis (methyl isocyanide)iron(II) have been recorded. Force constants have been computed using a modified Cotton-Kraihanzel force-field and the cases in which the iterative refinement procedure failed to converge are discussed in detail. The computed C–N stretching force-constants are found to be virtually independent of the configuration of the compound.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of the Chemical Society A: Inorganic, Physical, Theoretical
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
