Abstract

Abstract Infrared and Raman spectra of single crystal samples of naphthalene- d 8 have been recorded over the entire energy range of the fundamental vibrations. The spectra in all independent polarizations are presented. Depolarization ratios for the Raman lines in carbon tetrachloride and benzene solutions are reported. These data have been used to make a firm assignment of the molecular fundamentals; however, this experimental assignment remains incomplete. Where possible, comparisons have been made with the results of recent force-field calculations and the agreement is generally very good.

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