Versatile Coordination Mode of LiNaB8O13 and α- and β-LiKB8O13 via the Flexible Assembly of Four-Connected B5O10 and B3O7 Groups

Donghai An,Zhihua Yang,Danni Li,Zhi Su,Yi Sun,Yun Yang,Shilie Pan,Qingrong Kong,Huimin Chen,Miriding Mutailipu,Min Zhang

doi:10.1021/acs.inorgchem.5b02500

Versatile Coordination Mode of LiNaB8O13 and α- and β-LiKB8O13 via the Flexible Assembly of Four-Connected B5O10 and B3O7 Groups

Donghai An, Zhihua Yang + Show 9 more

https://doi.org/10.1021/acs.inorgchem.5b02500

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Journal: Inorganic chemistry	Publication Date: Dec 21, 2015
Citations: 17

Affiliation: Changji University, Xinjiang Technical Institute of Physics & Chemistry, Chinese Academy of Sciences, University of Chinese Academy of Sciences, Xinjiang Normal University

#Four-connected Nodes #Fundamental Building Block + Show 6 more

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Abstract

Three new alkali-metal mixed borates, LiNaB8O13, α-LiKB8O13, and β-LiKB8O13, containing a (3)∞[B8O13] three-dimensional network have been successfully synthesized. Their fundamental building block is [B8O16](8-) formed by the vertex-sharing [B5O10](5-) and [B3O7](5-) groups, which are topologically identical when they are considered as four-connected nodes. The viewpoints give us a feasible way to investigate the versatile structure assembly of borates with a complex network.

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