Variation of Nonlinear Refraction and Three-Photon Absorption of Indium-Tin Oxide Quantum Dot Thin Films and Solutions in Near Infrared Range.

Abstract

We characterize the nonlinear optical properties of indium-tin oxide (ITO) quantum dots (QDs) in the IR range using the Z-scan method. We present results of three-photon absorption (3PA), third harmonic generation (3HG), and Kerr-effect-induced nonlinear refraction in ITO QDs. Z-scan measurements were carried out for the QDs solution, while 3HG was demonstrated using QD thin films. The Kerr-induced nonlinear refractive index was analyzed along the 800-950 nm range showing an increase in this parameter from -6.7 × 10-18 to -1.5 × 10-17 m2 W-1. At longer wavelengths (1000-1100 nm), the higher-order effects started to contribute to a nonlinear refractive index. The 3PA coefficient at 950 nm was measured to be 1.42 × 10-25 m3/W2. We discuss the peculiarities in the wavelength-dependent variation of the coefficient of nonlinear absorption responsible for 3PA in the range of 800-1150 nm. Third harmonic generation was analyzed in the 1200-1550 nm spectral range. The absolute value of 3HG conversion efficiency in the 150 nm thick film at the wavelength of laser radiation (1350 nm) was estimated to be ~10-5.