Abstract
The nuclear half-life of $^{235m}\mathrm{U}$ has been reported to vary depending on the chemical environment. In this study, both the half-life and the internal-conversion (IC) electron energy spectrum were measured for $^{235m}\mathrm{U}$ with identical chemical environments for the first time. $^{235m}\mathrm{U}$ oxide and fluoride samples were subjected to these measurements, and clear differences in the half-life and the energy spectrum between these samples were observed. The peaks in the energy spectra were identified with a relativistic density functional theory calculation. The molecular orbital states of the $^{235m}\mathrm{U}$ oxide and fluoride, which were estimated from the energy spectra and the calculation, qualitatively explained the difference in the half-lives between the samples.
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