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https://doi.org/10.1016/s0040-4039(00)96523-7
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Cite Journal: Tetrahedron Letters |  Publication Date: Jan 1, 1987 |
 Citations: 10 |
Affiliation: University of Würzburg
The 2,2-dimethyl substituted 1,3-diradicals 5a-c possess significantly shorter triplet lifetimes (τ t) than the parent 1,3-cyclopentadiyl 3 , which is being rationalized on the basis of changes in the “through-bond” coupling and thus singlet-triplet energy splitting between the radical sites.
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