Utilization of waste tire derived activated carbon as CO2 capture and photocatalyst for CO2 conversion

Abstract

The aims of this research were to prepare activated carbon (AC) impregnated with tetraethylenepentamine (TEPA) for use in carbon dioxide (CO2) capture and to then develop the AC-TEPA sorbent with titanium dioxide (TiO2) as a catalyst for photocatalytic reduction. The AC was impregnated with TEPA at three loading levels (2.5, 5, and 10% [w/w]) and then examined for its CO2 adsorption capacity under an ambient temperature and atmospheric pressure. The use of 5% (w/w) TEPA-impregnated AC (AC_5T) provided the highest CO2 adsorption capacity and long-term operation with a regeneration ability for up to 10 cycles. Then, AC_5T-doped TiO2 (AC_5T-TiO2) was prepared as a photocatalytic reduction catalyst, since the presence of carbon and nitrogen in AC_5T could reduce the band gap energy and so enhance the photocatalytic reduction. In addition, the CO2-saturated AC_5T was used as a CO2 source that could be directly converted to valuable chemicals using the AC_5T-TiO2 catalyst under photocatalytic reduction. Products were obtained in both the liquid (methanol) and gaseous (methane, carbon monoxide, and hydrogen) phases. Accordingly, the challenge of this research was to make valuable products from CO2 and to manage waste tires, following the circular economy concept.