Utilization of tannery solid waste as an alternative biosorbent for acid dyes in wastewater treatment

Abstract

In this work the cattle hair waste (CHW), a solid waste that is generated in the tannery, was tested as an alternative new biosorbent of acid dyes, in order to add value to this waste that was discarded and suggesting a life cycle extension for this material from leather processing. Commercially activated carbon (CAC) was used to compare the sorption capacity of CHW. The sorption experiments were performed in laboratory scale with aqueous dye solutions of Acid Blue 161 (AB-161) and Acid Black 210 (AB-210) and were carried out under varying operational parameters including initial pH, adsorbent dosage, contact time, dye concentration and temperature. For the adsorption of the AB-161 and AB-210 dyes, the best kinetic model was described by general order kinetic. Liu isotherm model was well fitted with tested temperatures for AB-161 and AB-210 using CHW adsorbent. The maximum amounts of AB-161 dye adsorbed with CHW adsorbent were 104.78 (323K) and 26.29mgg−1 (303K) for AB-210. From the thermodynamic parameters for the adsorption of AB-161 and AB-210 with CHW and CAC indicated a not spontaneous endothermic process, with a physical reaction that dyes are arranged in orderly manner in the solid phase, resulting in a reduction in the disturbance of system.