Abstract

Zinc electroplating is a coating process controlled by several input process parameters. However, the commonly used input parameters for setting the process of zinc deposition are current density, temperature of the coating solution, zinc concentration, deposition time, and concentration of additives (conditioner and brightener). The power consumed in the zinc plating process, coating thickness, increase in coating mass, and corrosion resistance are considered to be outputs or zinc coating parameters. They are widely used when the zinc coating requirements are based on the coating process cost, coating process speed, corrosion resistance, and coating thickness. This paper seeks to determine regression models by the response surface method (RSM) that relate the zinc coating parameters to the input parameters in steel screws. When considering the coating requirements of cost, coating process speed, corrosion resistance, and coating thickness, the optimal input parameters were found by using a multi-response surface (MRS). Input parameters of 0.3 amps/dm2, 20.0 °C, 13.9 g/L, 45 min, 28.5 mL/L, and 2.8 mL/L, respectively (relative to the commonly used input parameters detailed above), were obtained when considering the cost. Considering minimization of the deposition time, the input parameters obtained were 0.5 amps/dm2, 24.6 °C, 13.9 g/L, 45 min, 26.9 mL/L, and 1.1 mL/L, respectively. The optimal inputs to maximize the corrosion resistance were 0.6 amps/dm2, 32.4 °C, 14.0 g/L, 45 min, 28.7 mL/L, and 2.5 mL/L, respectively. Finally, when maximizing the coating thickness, the inputs were 0.7 amps/dm2, 38.4 °C, 12.2 g/L, 45 min, 26.5 mL/L, and 1.5 mL/L, respectively.

Highlights

  • Zinc electroplating is one of the most commonly used methods to protect steel from the corrosion process

  • While considering zinc coating requirements based on cost, manufacturing speed, corrosion resistance, and coating thickness, the optimal input process parameters were found by using the multi-response surface (MRS) with the desirability functions

  • Each ofeach the phosphate screws was weighed on a precision of coating toapplied be applied to steel of the phosphate screws was weighed on a balance to determine its initial mass prior to application of the zinc coating

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Summary

Introduction

Zinc electroplating is one of the most commonly used methods to protect steel from the corrosion process. The effect of different factors, such as temperature, current density, time, zinc concentration, and additive concentration, on the corrosion rate has not been proven yet This process involves the electrolytic deposition of a thin coating of zinc onto the surface of the metal to be protected, which is known as a substrate. A group of regression models that are based on the RSM were used to relate the zinc coating requirements (outputs) to the zinc coating process parameters (inputs) The latter were current density (ρ), temperature of the coating solution (T), zinc concentration (C), deposition time (t), concentration of Additive 1 (Envirozin Conditioner (CA1)), and concentration of Additive 2 (Envirozin 100 Initial Brightener (CA2)). While considering zinc coating requirements based on cost, manufacturing speed, corrosion resistance, and coating thickness, the optimal input process parameters were found by using the multi-response surface (MRS) with the desirability functions. The optimization portion of the R package v.1.6 looks for a combination of factors (or weights in the range 1–3) that simultaneously satisfy the optimization criteria of all responses and inputs

Electroplating Process Factors Examined by Use of RSM
Results
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Conventional
Design of Experiments
Results and Discussion
Conclusions

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