Using light to probe hypersound in porous materials systems

Abstract

An overview of the technique of Brillouin light scattering spectroscopy and its application to the study of hypersound in micro- and mesoporous materials systems will be presented. Particular emphasis will be placed on results obtained from light scattering experiments on porous silicon-based structures. For porous silicon films, it was found that the acoustic phonon velocities and elastic properties depend strongly on the film porosity and morphology. Brillouin studies of porous silicon superlattices with periodicity on the order of the hypersound wavelength reveal that these structures behave as hypersonic phononic crystals, while those with smaller modulation wavelengths act as effective elastic media. New results on localized acoustic modes in porous silicon multilayers will also be discussed. Collectively, these studies provide a detailed picture of hypersound propagation in porous silicon systems and demonstrate the utility of Brillouin spectroscopy for probing acoustic phonon behavior in this challenging class of materials. [This work was supported by the Canada Foundation for Innovation, Memorial University of Newfoundland, and the Natural Sciences and Engineering Research Council of Canada.]