Use of magnetic susceptibility to assess metals concentration in soils developed on a range of parent materials

Abstract

This research was conducted to evaluate the utilization of magnetic susceptibility measurements in the assessment of metal concentrations in soils developed on a range of parent materials in northwestern Iran. Eighty surface soil samples were collected from eight parent rocks including ultrabasic rocks, basalt, andesite, granite, marl, limestone, Qom formation, and shale. The collected samples were assessed to determine magnetic susceptibility at low frequency (χlf) and concentrations of some metals comprising chromium (Cr), iron (Fe), copper (Cu), nickel (Ni), zinc (Zn), cobalt (Co), and manganese (Mn). The results showed that the highest levels of metals and χlf were observed in basic and ultrabasic soils. Strong positive correlations (P < 0.01) detected between χlf and Fe (0.87), Mn (0.78), Zn (0.74), Ni (0.90), Co (0.78), and Cr (0.90) in all samples indicated a potential for using magnetic susceptibility in semi-quantitative estimation of metal concentrations in soils of natural ecosystems. Multiple linear regression between metal contents and χlf showed that Ni, Zn, Mn, and Co could explain 77% of the total variance in χlf in the study area. K-means cluster analysis categorized the studied soils into three groups based on metals and χlf variability. Clustering of soils based on their parent rocks and use of further magnetic measures, i.e., saturation isothermal remanent magnetization (SIRM), isothermal remanent magnetization (IRM100mT) and natural remanent magnetization (NRM) are expected to improve the accuracy of metal concentration predictions in natural soils of the study area.