Abstract
Urothermal reaction of Zn(NO3)2·6H2O, Htrz and NH2H2pdc or H2pdc affords two new compounds, namely [Zn2(NH2bdc)(trz)2]n·2n(e‐urea) (1) and [Zn4(bdc)2(trz)4(H2O)(e‐urea)]n·n(e‐urea) (2) (Htrz = 1,2,4‐triazole, NH2H2bdc = 2‐aminoterephthalic acid, H2bdc = terephthalic acid, e‐urea = 1,3‐ethyleneurea). X‐ray structural analyses revealed that both compounds 1 and 2 feature e‐urea‐templated 3D pillar‐layer framework with 2D ZnII‐triazole layer and 6‐connected pcu topological network. These two compounds not only have high thermal stabilities but also show intense luminescence at room temperature.
Published Version
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