Abstract
Dechlorane plus (DP) is a chlorinated flame retardant with high production volume (HPV) and is widely used in our daily necessities. In the present study, a laboratory-scale microcosm was built up to simulate the uptake, depuration, bioaccumulation, and stereoselective enrichment of DP in a lower concentration and equilibration condition. Common carp (Cyprinus carpio) were used for 32days exposure and 32days depuration. The concentration ratios of syn-DP to total DP (fsyn values) in fish examined were lower than that in commercial products. Rate constants of uptake (kS) and elimination (ke) for the syn- and anti-DP were calculated using a first-order kinetic model. The uptake rate constants of syn- and anti-DP were 0.63 and 0.89day-1, respectively. The depuration rate constants of syn-DP (0.11day-1) were similar to anti-DP (0.096day-1), suggesting that anti-DP is absorbed faster than syn-DP by common carp. The estimated bioconcentration factors for both syn-DP (5700L/kg) and anti-DP (9300L/kg) were higher than the bioconcentration hazard criteria outlined in the Stockholm Convention, suggesting the bioconcentration potential to aquatic organisms for DP.
Published Version
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