Abstract

The reactions of the BrO radical with hydrogen bromide, BrO + HBr → HOBr + Br (R4) and with HCHO, BrO + HCHO → HOBr + HCO (R5) have been studied at 298 K, 1 atm. pressure in an environmental chamber. No conclusive evidence for the occurrence of either reaction was found and upper limits for both reaction rate coefficients are reported (k4, k5 <4 × 10−15 cm³ molecule−1 s−1). These upper limits are about 4–5 times lower than recent estimates [Hansen et al., 1999a,b].

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