Unveiling the underlying mechanism of unusual thermal conductivity behavior in multicomponent high-entropy (La0.2Gd0.2Y0.2Yb0.2Er0.2)2(Zr1-xCex)2O7 ceramics

Abstract

Previously, the research on thermal conductivity of ceramic thermal barrier coatings mainly focused on phonon and photon thermal conductivity (thermal radiation effect). However, electrical conductivity is remarkable in some systems. Hence, the contribution of phonon, photon and electronic heat conduction to thermal conductivity of high-entropy systems was evaluated in this study. The (La0.2Gd0.2Y0.2Yb0.2Er0.2)2(Zr1-xCex)2O7 (x = 0–0.5) high-entropy ceramics with single defective fluorite structure were successfully prepared via a solid reaction method. Below 600 °C, the thermal conductivities decrease with increasing temperature for x = 0.1–0.5 components, then reveal a drastic temperature dependent increase. Moreover, the composition dependent thermal conductivities are also unusual based on the conventional phonon thermal conduction mechanism. The increased electronic thermal conductivity, improved photon thermal conductivity (at high temperatures) and reduced phonon-grain boundary scattering should be responsible for the unusual thermal conductivity behavior. This can be verified by the significantly increased electrical conductivity, optical transmittance and grain size, as well as reduced emissivity for (La0.2Gd0.2Y0.2Yb0.2Er0.2)2(Zr1-xCex)2O7 high-entropy ceramics. The present study also broadens the way to investigate the thermal conductivity of ceramic thermal barrier coatings, and is helpful to design thermal barrier coatings with low thermal conductivity.