Unveiling microplastics from zippers: Characterisation and visualisation through Raman imaging analysis

Abstract

Microplastics have emerged as a global concern due to the increased plastic contamination found in a variety of sources. Herein we unveil microplastics released from plastic zippers that can generally be found in our clothes and textiles. We first employ a scanning electron microscope (SEM) to visualise the scratches developed on the zipper teeth and the derived particles. We then use Raman imaging to identify and simultaneously visualise the plastics from the chemical or molecular spectrum window. Based on hundreds to thousands of spectra, rather than a single spectrum or even a single peak that works as just a pixel in the image, imaging analysis can significantly increase the signal-to-noise ratio. Furthermore, the non-uniform distribution of components or multi-components can also be effectively imaged to avoid the possible bias from the single-spectrum analysis. The challenge to convert the hundreds to thousands of spectra of a hyperspectral matrix to an image is also discussed, and chemometrics is adopted and recommended to further improve the signal-to-noise ratio. The co-ingredient of titanium oxide in the zipper teeth/sewing lines is also effectively identified by Raman imaging. Based on the effective characterisation, we estimate that up to ~410 microplastics could be potentially released during each time of on-off zipping, although the variation can be expected and depends on several other factors. This study reminds us to be aware of the potential contamination derived from similar types of microplastic sources in our daily lives.