Abstract
The Suzuki-Miyaura coupling polymerization of p-dibromophenylene and m-phenylenediboronic acid ester, as well as m-dibromophenylene and p-phenylenediboronic acid ester, and the combination of two meta-phenylene monomers in the presence of the t-Bu3PPd(0) catalyst selectively afforded cyclic polyphenylenes with polyphenylene bearing boronate moieties at both ends when excess dibromophenylene was used.
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