Abstract
The major species detected by e.s.r. spectroscopy in γ-irradiated sulphuryl chloride at 77 K is thought to be SO2Cl2–. The 33S and 35Cl hyperfine components and the g-tensor components are in accord with this suggestion, and show that the radical anion is comparable with others in this class, having the unpaired electron primarily on sulphur (ca. 76%) with a very high 3s-character (ca. 29 %), and on the two equivalent chlorine atoms with a high 3p-character (ca. 23 %). The form of the molecular orbital involved is discussed.
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