Uniform zinc-ion deposition regulated by thin sulfonated poly(ether ketone) layer for Stabilizing Zn anodes

Abstract

Aqueous zinc-ion batteries (AZIBs) have been getting lots of attention in the field of large scale energy storage owing to their low cost, large capacity and excellent safety. However, Zn anodes have serious dendritic growth and corrosion hydrogen evolution issues, which hinder their further application. Herein, a simple drop-coating technique was used to build a thin sulfate poly(ether ketone) (SPEEK) solid-electrolyte interphase (SEI) on the surface of the Zn anode to address these issues. The sulfonated group (−SO3 −） in SPEEK can provide rich coordination sites for Zn2+, controlling the uniform deposition of Zn2+. Therefore, the polymer SEI can block electrolytes and homogenize the Zn2+ flux, resulting that the modified Zn (SPEEK@Zn) anode could effectively limit the formation of dendrites and side reactions. At a current density of 0.5 mA cm−2, SPEEK@Zn electrodes can maintain an ultra-long plating/stripping cycle life of 1000 h. Full batteries based on SPEEK@Zn have more superior cycle stability than the bare ones. This approach offers a straightforward and scalable remedy for high-performance Zn anode batteries.