Abstract

The blending of steel slag powder with cement can mitigate the carbon footprint of cementitious composites. The rheological properties of cement pastes are well known to be related to interparticle forces. However, the magnitude of the interparticle force depends on many physico-chemical factors. The influence of various factors on interparticle forces is not yet clear, making it difficult to control the rheological properties. In this paper, the interparticle force of steel slag powder blended cement paste was quantified and its relationships with dynamic rheological properties and basic physico-chemical parameters were explored. By means of this, the interparticle force was confirmed to could explain the effect of steel slag powder on the dynamic rheological properties of cement paste within 1 h. Moreover, how physico-chemical parameters affect the interparticle forces was clarified. A cement paste with large particle size and apolar surface energy, as well as small potential square, Debye length and small polar surface energy, can exhibit large interparticle force and high dynamic yield stress and plastic viscosity. A simple formula calculating interparticle force from basic parameters was proposed, which is believed to effectively and practically regulate the interparticle force. The relationships between interparticle forces, physico-chemical parameters, and rheological properties provide an effective reference for regulating the dynamic rheological properties of cement paste through fundamental parameters.

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