Abstract
In the title triangulo-triruthenium compound, [Ru3(C6H12Cl3O3P)(CO)11], one equatorial carbonyl ligand is substituted by a monodentate phosphite ligand, leaving one equatorial and two axial carbonyl ligands on one Ru atom. The remaining two Ru atoms each carry two equatorial and two axial terminal carbonyl ligands. In the crystal structure, the molecules are linked into a one-dimensional column along [100] by intermolecular C—H⋯O hydrogen bonds.
Highlights
In the title triangulo-triruthenium compound, [Ru3(C6H12Cl3O3P)(CO)11], one equatorial carbonyl ligand is substituted by a monodentate phosphite ligand, leaving one equatorial and two axial carbonyl ligands on one Ru atom
As part of our ongoing studies on phosphite n n substituted triangulo-triruthenium clusters (Shawkataly et al, 1991, 2010), we report the structure of the title compound
Symmetry codes: (i) −x+2, −y+1, −z+1; (ii) −x+1, −y+1, −z+1
Summary
Rint = 0.037 a Chemical Sciences Programme, School of Distance Education, Universiti Sains. 11800 USM, Penang, Malaysia, and bX-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia. R factor = 0.030; wR factor = 0.120; data-to-parameter ratio = 34.9. In the title triangulo-triruthenium compound, [Ru3(C6H12Cl3O3P)(CO)11], one equatorial carbonyl ligand is substituted by a monodentate phosphite ligand, leaving one equatorial and two axial carbonyl ligands on one Ru atom. The remaining two Ru atoms each carry two equatorial and two axial terminal carbonyl ligands. The molecules are linked into a one-dimensional column along [100] by intermolecular C—H O hydrogen bonds
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