Abstract
A highly sensitive amperometric hydrazine monitoring sensor offering an ultrawide dynamic range of 5 μM to 1 M in alkaline media (e. g., 1 M KOH) was developed via co-electrodepositing iridium-nickel alloy nanoparticles (NPs) functionalized with multi-walled carbon nanotubes (Ir-Ni-MWCNTs) on a disposable screen-printed carbon electrode. The synergistic interaction of MWCNTs with Ir-Ni alloy NPs resulted in enlarged active surface area, rapid electron transfer, and alkaline media stability with an onset potential of -0.12 V (vs. Ag/AgCl) toward hydrazine oxidation. A limit of detection for hydrazine was 0.81 μM with guaranteed reproducibility, repeatability, and storage stability alongside a superb selectivity toward ethanolamine, urea, dopamine, NaBH4 , NH4 OH, NaNO2 , and Na2 CO3 . The sensor was finally applied to on-site monitoring of the carbon-free hydrazine concentration at the anode and cathode of a hydrazine fuel cell, providing more insight into the hydrazine oxidation process during cell operation.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
