Abstract

We report a survey of samples containing ultrathin layers of CdSe embedded in ZnSe or ZnS 0.06Se 0.94 matrices. CdSe single quantum wells (SQW) with well widths in the range 0.3–3 ML show several bands in the photon energy range from 1.7 to 2.4 eV. Similar bands have been attributed recently to self-organised quantum dots. Temperature-dependent photoluminescence (PL) shows that the bands in our samples vanish, without significant peak shift, at moderately high temperatures. Preliminary time-resolved PL shows that they also have relatively long lifetimes (ca. 30−250 ns). In all samples, the SQW exciton band lying at higher energies shows line narrowing with increasing temperature. Variations due to quantum-well thickness induce a correlation between the luminescence peak energy and the optical bandwidth which may be used to systematise our observations.

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