Abstract
The design and construction of an optical instrument is described to enable accurate and reliable resonance Raman scattering and photoluminescence measurements to be acquired in the 200–700 nm (1.77–6.2 eV) wave band, with minimum user intervention between changes of the excitation wavelength. An f/6 line or point focus is formed at the sample. f/2 achromatic catadioptric optics image the scattered light to the entrance slit of an f/7.5 spectrometer. An ultraviolet sensitive charge coupled device camera enables imaging and alignment of samples within the excitation laser region, providing an imaging resolution of better than 13 μm (results presented elsewhere suggest a resolution limit of 7 μm). The use of an aperture plate allows pseudo-confocal operation, leading to considerable improvement in depth discrimination when interrogating extended volume scatterers. This mode of operation furthermore eliminates stray light derived from the Rayleigh line, thereby enabling line focus spectra to be obtained to very low wave numbers. The optics present a unique method of interrogating a sample with an extended lateral and well-defined axial interaction region with a high collection efficiency (optical throughput of >41%), simultaneously offering broadband achromatic spectral response in collection from 200 to 700 nm.
Published Version
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