U(VI) adsorption on hematite nanocrystals: Insights into the reactivity of {001} and {012} facets

Abstract

Predicting the environmental behavior of U(VI) relies on identification of its local coordination structure on mineral surfaces, which is also an indication of the intrinsic reactivity of the facet. We investigated the adsorption of U(VI) on two facets ({001} and {012}) of hematite (α-Fe2O3) by coupling experimental, spectroscopic and theoretical studies. Batch experiments results indicate higher removal capacity of the hematite {012} facet for U(VI) with respect to the {001} facet, due to the existence of extra singly and triply coordinated oxygen atoms with higher reactivity on the {012} facet while only doubly coordinated oxygen atoms exist on the {001} facet. The formation of surface complexes containing U(VI) is responsible for the appearance of a new sextuplet by Mössbauer spectra. The local structures of an inner-sphere edge-sharing bidentate complex on the hematite {001} and a corner-sharing complex on the {012} facet was deciphered by extended X-ray absorption fine structure spectroscopy. The chemical plausibility of the proposed structures was further verified by density functional theory calculation. This finding reveals the important influence of surficial hydroxyl groups reactivity on ions adsorption, which is helpful to better understand the interfacial interactions and to improve the prediction accuracy of U(VI) fate in aquatic environments.