Two new POM-based compounds containing a linear tri-nuclear copper(II) cluster and an infinite copper(II) chain, respectively

Abstract

Abstract Using the pendent organic ligand 1-butyl-1H-(1,3,4)triazole (btz), two new polyoxometalate (POM)-based compounds, [Cu3(btz)6(H2O)4(H3P2W18O62)2]·6H2O (1) and [Cu2(btz)(tz)(H2O)2(SiMo12O40)]·5H2O (2) (tz=1H-(1,3,4)triazole), have been synthesized under hydrothermal conditions. In compound 1, three CuII ions are fused by six btz ligands to form a linear tri-nuclear CuII cluster, with water as bridging molecules. Two Wells-Dawson anions offer two terminal O atoms to link two apical CuII atoms of this tri-nuclear cluster. In compound 2, the btz and tz molecules connect CuII ions to construct an infinite CuII chain still with water molecules as bridges. The adjacent chains are linked by one type of POM anions to build a 2D grid-like layer. Considering the long-range coordinative Cu–O bonds, the other types of POM anions connect adjacent layers to form a 3D framework. The electrochemical and photocatalytic properties of compounds 1 and 2 were also studied.