Abstract
The title coordination polymer, poly[diaqua(1,10-phenanthroline)(μ3-pyrazole-3,5-dicarboxylato)tricopper(II)], [Cu3(C5HN2O4)2(C12H8N2)2(H2O)2]n, was hydrothermally synthesized and structurally characterized. It consists of linear trinuclear copper(II) clusters of [Cu3(pdc)2(phen)2(H2O)2] units (H3pdc = pyrazole-3,5-dicarboxylic acid and phen = 1,10-phenanthroline), in which two pdc3− ligands chelate three CuII ions with the central CuII ion on an inversion center. An infinite two-dimensional sheet structure is constructed by connecting adjacent linear trinuclear copper(II) units through coordination bonds between the central CuII atom and an O atom of the carboxylate group coordinated to the terminal CuII atom from the pdc3− ligand.
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