Abstract
An unusual compound Zn 1.5 (Hsdpa)(bpy) 1.5 (H 2 O) 4 ( 1) comprising two isolated coordination polymers has been obtained by hydrothermal reactions, in which helical channels of a 3D host framework A [Zn(Hsdpa)(bpy)(H 2 O) 2 ] − are filled with the guest infinite 1D polymer chains B [Zn 0.5 (bpy) 0.5 (H 2 O) 2 ] + . ► A 3D coordination polymer comprises two isolated coordination. ► Weak interactions between host and guest stabilize the structure. ► Helical voids of the host are filled by the 1D guest metal-organic polymers. ► The luminescent properties of d 10 metal-organic polymers.
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