Synthesis, Characterisation and Magnetic Properties of a One-Dimensional Iron(II) Coordination Polymer

Abstract

A new iron(II) coordination polymer, [FeCl2(NC7H9)2(N2C12H12)], has been synthesized under solvothermal conditions and structurally characterized by single-crystal X-ray diffraction. This material crystallizes in the monoclinic space group C2/c, with a = 11.2850(6), b = 13.8925(7), c = 17.0988(9) A and β = 94.300(3)o (Z = 4). The crystal structure consists of neutral zig-zag chains, in which the iron(II) ions are octahedrally coordinated. The infinite polymer chains are packed into a three-dimensional structure through C–H···Cl interactions. Magnetic susceptibility measurements reveal the existence of weak antiferromagnetic interactions between the iron(II) ions. The effective magnetic moment, μ eff = 5.33 μ B , is consistent with a high-spin iron(II) configuration. The crystal structure of the coordination polymer [FeCl2(NC7H9)2(N2C12H12)] consists of neutral zig-zag chains, in which the iron(II) ions are octahedrally coordinated.