Two-Dimensional Zeolites-Potential Catalysts for Biomass Valorization.

Abstract

Valorization of biomass and biomass-derived molecules has become a viable route to get fuels and useful chemicals as fossil feedstocks are dwindling and the demand for renewable feedstocks and sustainable energy sources are rising. Zeolites have been promising catalysts for biomass conversion owing to their structural features and active sites. However, the use of conventional zeolites was limited due to molecular diffusion constraints, which paved the way for the emergence of two-dimensional (2D) zeolites. The high external surface area, bimodal porosity (micropores and mesopores), and 2D structure of these zeolites envisage smooth diffusion of bulky molecules, enhanced accessibility to active sites, and slow deactivation, which are benefits in the valorization of biomass. In this brief review, current advancements in the use of layered 2D zeolites for biomass conversions are discussed. The relationship between the structural features and the catalytic potential of 2D zeolites in some of the major biomass conversion processes like pyrolysis, hydrodeoxygenation, alkylation, acetalization, condensation, and dehydration is discussed and multistep reactions that proceed via a cascade mechanism are highlighted.